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Jul 20, 2015  Click the Bluetooth tab, scroll down to the ‘Related Settings’ and click ‘More Bluetooth options’. This will open the Bluetooth settings window. In the very first tab ‘Options’ you will see a ‘Discovery’ section with an ‘Allow Bluetooth devices to find this PC’ option. Pair iPhone or any phone with a Windows 10 PC via Bluetooth. In a few seconds, your phone/iPhone’s name should appear in manage Bluetooth devices section. Step 5: Click on your iPhone/phone’s name to see the Pair button. Click the Pair button. Step 6: Finally, you will see the following screen on your Windows 10 PC. As you can see, the dialog shows a passcode.